Q1 Research Application · Frontier Focus

First triple-functional polyoxometalate Cs10.6[H2.4GeNb13O41] for highly selective production of methyl levulinate directly from cellulose

This Cellulose paper (2018) is indexed as a Xianghu equipment application case for XH-800S; key result: Conversion 86.0%.

View DOI Back to Library Chinese Solution
Paper ID 383
Application Focus Brønsted-Lewis
Key Result Conversion 86.0%
Core Condition Temperature 165°C / 190°C
Paper ID
383
Journal
Cellulose
Impact Factor
4.21
CAS Zone
Zone 1
Year
2018
DOI
10.1007/s10570-018-2037-3
Equipment Model
XH-800S
Affiliations
Northeast Normal University; Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, PR China; School of Chemistry, University of Edinburgh, Edinburgh EH3FJ, UK; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun 130022, PR China
Research Directions
Brønsted-Lewis

Fact Snapshot

  • Paper: First triple-functional polyoxometalate Cs10.6[H2.4GeNb13O41] for highly selective production of methyl levulinate directly from cellulose
  • Equipment: XH-800S
  • Source: Cellulose, 2018
  • Research direction: Brønsted-Lewis
  • Core conditions: Temperature 165°C / 190°C and Time 3 h / 10 h / 12 h
  • Key results: Conversion 86.0%, Conversion 13.5%, and Conversion 85.2%

Research Abstract

First triple-functional polyoxometalate Cs10.6[H2.4GeNb13O41] for highly selective production of methyl levulinate directly from cellulose was published in Cellulose (2018) and is indexed as a Xianghu Q1 application case for XH-800S. The structured source links this paper to Brønsted-Lewis. Core operating conditions include Temperature 165°C / 190°C and Time 3 h / 10 h / 12 h. Key reported results include Conversion 86.0%, Conversion 13.5%, and Conversion 85.2%. The DOI recorded for this paper is 10.1007/s10570-018-2037-3.

Research Background and Problem

The paper is positioned around Brønsted-Lewis. The equipment record identifies XH-800S as the Xianghu instrument context for this application case. The source affiliation record includes Northeast Normal University and Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, PR China.

Equipment Use and Experimental Conditions

ItemParameter
Temperature165°C / 190°C
Time3 h / 10 h / 12 h

Key Result

Conversion 86.0%
Conversion 13.5%
Conversion 85.2%
Yield 53.0%
MetricResult
Conversion86.0%
Conversion13.5%
Conversion85.2%
Yield53.0%
Yield55.4%
Yield85.6%

Evidence Details

Microwave-method evidence

Microwave-method evidence: source values include 0.1 g, 6 mL, 165°C, 3 h, 10 h, 0.13 g, 0.7 g, 30 min, 10 mL, 1 mL, 0°C, 12 h.

Yield evidence

Yield evidence: source values include 85.6%, 100%, 60.4%, 93.0%, 46.9%, 39.8%, 36.4%.

Stability evidence

Stability evidence: source values include 86.0%, 53.0%, 82.0%, 50.5%, 4.0%, 2.5%.

Yield evidence

Yield evidence: source values include 165°C, 3 h, 85.2%, 55.4%, 10 h.

Additional source evidence

Additional source evidence: source values include 13.5%, 65.0%, 46.0%, 40.0%, 86.0%.

Yield evidence

Yield evidence: source values include 0.05 g, 190°C, 18 h, 24%.

Yield evidence

Yield evidence: source values include 1 g, 85.0%, 52.5%.

Additional source evidence

Additional source evidence: source values include 0.1325 g, 0.0292 g.

Additional source evidence

"The reaction was also carried out in an XH-800C computer microwave apparatus, equipped with sealed Teflon reaction vessels, an internal temperature sensor, and a pressure sensor."

Mechanism / Method Highlights

  • Method context: Temperature 165°C / 190°C and Time 3 h / 10 h / 12 h.
  • Microwave-method evidence: source values include 0.1 g, 6 mL, 165°C, 3 h, 10 h, 0.13 g, 0.7 g, 30 min, 10 mL, 1 mL, 0°C, 12 h
  • Yield evidence: source values include 85.6%, 100%, 60.4%, 93.0%, 46.9%, 39.8%, 36.4%
  • Stability evidence: source values include 86.0%, 53.0%, 82.0%, 50.5%, 4.0%, 2.5%
  • Reported outcome: Conversion 86.0%, Conversion 13.5%, Conversion 85.2%, and Yield 53.0%.

Application Value

  • Positions XH-800S in a peer-reviewed Q1 research application.
  • Highlights quantitative evidence: Conversion 86.0%, Conversion 13.5%, and Conversion 85.2%.
  • Records source affiliations: Northeast Normal University and Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, PR China.

Related Equipment

XH-800SE Microwave Hydrothermal Synthesizer
XH-800SE Microwave Hydrothermal Synthesizer

FAQ

Which Xianghu instrument is covered by this page?
The structured source records XH-800S for this paper.
What is the main application direction?
The source tags this paper under Brønsted-Lewis.
Which publication does this case come from?
It comes from Cellulose (2018), DOI 10.1007/s10570-018-2037-3.
Citation
First triple-functional polyoxometalate Cs10.6[H2.4GeNb13O41] for highly selective production of methyl levulinate directly from cellulose
Cellulose, 2018
DOI: 10.1007/s10570-018-2037-3