Q1 Research Application · Frontier Focus

Quasi-MIL-101(Fe) with rich oxygen vacancies for boosted heterogeneous photo-Fenton reaction

This Separation and Purification Technology paper (2025) is indexed as a Xianghu equipment application case for XH-100A; key result: Removal 100.0 %.

View DOI Back to Library Chinese Solution
Paper ID 181
Application Focus MOF
Key Result Removal 100.0 %
Core Condition Temperature 150.0 °C / 250 °C / 300 °C
Paper ID
181
Journal
Separation and Purification Technology
Impact Factor
9
CAS Zone
Zone 1
Year
2025
DOI
10.1016/j.seppur.2025.132510
Equipment Model
XH-100A
Affiliations
Beijing University of Civil Engineering and Architecture
Research Directions
MOF

Fact Snapshot

  • Paper: Quasi-MIL-101(Fe) with rich oxygen vacancies for boosted heterogeneous photo-Fenton reaction
  • Equipment: XH-100A
  • Source: Separation and Purification Technology, 2025
  • Research direction: MOF
  • Core conditions: Temperature 150.0 °C / 250 °C / 300 °C, Microwave power 750.0 W, and Time 10.0 min / 84.0 h
  • Key results: SMX removal 100.0 %, COD removal 54.4 %, and Photo-Fenton degradation rate 28-fold

Research Abstract

Quasi-MIL-101(Fe) with rich oxygen vacancies for boosted heterogeneous photo-Fenton reaction was published in Separation and Purification Technology (2025) and is indexed as a Xianghu Q1 application case for XH-100A. The source record connects it with MOF. Core operating conditions include Temperature 150.0 °C / 250 °C / 300 °C, Microwave power 750.0 W, and Time 10.0 min / 84.0 h. Key reported results include SMX removal 100.0 %, COD removal 54.4 %, and Photo-Fenton degradation rate 28-fold.

Research Background and Problem

The paper is positioned around MOF. The equipment record identifies XH-100A as the Xianghu instrument context for this application case. The source affiliation record includes Beijing University of Civil Engineering and Architecture.

Equipment Use and Experimental Conditions

ItemParameter
Temperature150.0 °C / 250 °C / 300 °C
Microwave power750.0 W
Time10.0 min / 84.0 h

Key Result

Removal 100.0 %
Removal 54.4 %
Photo-Fenton degradation rate 28-fold
MetricResult
Removal100.0 %
Removal54.4 %
Photo-Fenton degradation rate28-fold

Evidence Details

Equipment and method evidence

Typically, a mixture of terephthalic acid (H2BDC) (1.380 g) and FeCl3⋅6H2O (2.244 g) was dissolved into a three-necked flask with 120.0 mL of DMF, which was reacted in XH-100B (Xianghu Co., Beijing) microwave oven fitted with a reflux condenser. The mixed solution was heated by microwave to 150.0 ◦C (750.0 W) for 10.0 min.

Microwave-method evidence

Microwave-method evidence: source values include 1.380 g, 2.244 g, 120.0 mL, 150.0 °C, 750.0 W, 10.0 min. Entities: XH-100B, MIL-101.

Additional source evidence

Additional source evidence: source values include 250 °C, 300 °C, 350 °C, 400 °C, 2.0 h. Entities: Qx-MIL-101, Q350-MIL-101.

Release-kinetics evidence

Release-kinetics evidence: source values include 20.0 min, 10.0 mg, 84.0 h, 100.0 %. Entities: Q350-MIL-101.

Release-kinetics evidence

Release-kinetics evidence: source values include 1.14 min, 0.04 min, 28 fold. Entities: Q350-MIL-101, MIL-101.

Source evidence

Q350-MIL-101(Fe) exhibited the best catalytic performance among all as-synthesized catalysts, which accomplished 100.0 % SMX removal efficiency within 3.0 min.

Additional source evidence

Additional source evidence: source values include 100.0 %, 27.6 %, 16.0 %.

Additional source evidence

Additional source evidence: source values include 10.0 mg, 50.0 mL, 30 %.

Additional source evidence

Additional source evidence: source values include 2.21 nm, 5.24 nm. Entities: Q350-MIL-101, MIL-101.

Structured key result

COD removal: 54.4 %

Mechanism / Method Highlights

  • Method context: Temperature 150.0 °C / 250 °C / 300 °C, Microwave power 750.0 W, and Time 10.0 min / 84.0 h.
  • Equipment and method evidence: Typically, a mixture of terephthalic acid (H2BDC) (1.380 g) and FeCl3⋅6H2O (2.244 g) was dissolved into a three-necked flask with 120.0 mL of DMF, which was reacted in XH-100B (Xianghu Co., Beijing) microwave oven fitted with a reflux condenser. The mixed solution was heated by microwave to 150.0 ◦C (750.0 W) for 10.0 min
  • Microwave-method evidence: source values include 1.380 g, 2.244 g, 120.0 mL, 150.0 °C, 750.0 W, 10.0 min. Entities: XH-100B, MIL-101
  • Additional source evidence: source values include 250 °C, 300 °C, 350 °C, 400 °C, 2.0 h. Entities: Qx-MIL-101, Q350-MIL-101
  • Reported outcome: SMX removal 100.0 %, COD removal 54.4 %, and Photo-Fenton degradation rate 28-fold.

Application Value

  • Provides a peer-reviewed SoarNova / Xianghu Q1 application case for XH-100A.
  • Supports English discovery around MOF.
  • Preserves quantitative result evidence: SMX removal 100.0 %, COD removal 54.4 %, and Photo-Fenton degradation rate 28-fold.
  • Maintains source-level evidence details: Equipment and method evidence: Typically, a mixture of terephthalic acid (H2BDC) (1.380 g) and FeCl3⋅6H2O (2.244 g) was dissolved into a three-necked flask with 120.0 mL of DMF, which was reacted in XH-100B (Xianghu Co., Beijing) microwave oven fitted with a reflux condenser. The mixed solution was heated by microwave to 150.0 ◦C (750.0 W) for 10.0 min, Microwave-method evidence: source values include 1.380 g, 2.244 g, 120.0 mL, 150.0 °C, 750.0 W, 10.0 min. Entities: XH-100B, MIL-101, Additional source evidence: source values include 250 °C, 300 °C, 350 °C, 400 °C, 2.0 h. Entities: Qx-MIL-101, Q350-MIL-101, and Release-kinetics evidence: source values include 20.0 min, 10.0 mg, 84.0 h, 100.0 %. Entities: Q350-MIL-101.

Related Equipment

XH-100A+ Microwave Catalytic Synthesis/Extraction System
XH-100A+ Microwave Catalytic Synthesis/Extraction System

FAQ

Which Xianghu instrument is covered by this page?
The structured source records XH-100A for this paper.
What is the main application direction?
The source tags this paper under MOF.
Which publication does this case come from?
It comes from Separation and Purification Technology (2025), DOI 10.1016/j.seppur.2025.132510.
Citation
Quasi-MIL-101(Fe) with rich oxygen vacancies for boosted heterogeneous photo-Fenton reaction
Separation and Purification Technology, 2025
DOI: 10.1016/j.seppur.2025.132510